一种大量元素水溶肥料的制备及其在玉米上的喷施效果

根据玉米需肥特性设计氮磷钾比例,制备了含中微量元素的大量元素水溶肥料,产品氮、磷、钾比例为2∶1∶4,属于高钾中氮低磷型.在河北省安平县前子文村和浙江省新昌县孟家塘村玉米上开展了叶面喷施试验.结果表明:玉米生物学性能得到改善,玉米产量、出籽率、百粒重与容重得到提高;与空白对照相比,平均增产率为5.45％,平均纯增收896.40元/公顷,平均产投比为5.43∶1.     

Phase and microstructure evolution of Sc2O3–CeO2 –ZrO2ceramics in Na2SO4 + V2O5 molten salts

In this study, the destabilization resistance of Sc₂O₃ and CeO₂ co-stabilized ZrO₂ (SCZ) ceramics was tested in Na₂SO₄ + V₂O₅ molten salts at 750°C–1100 °C. The phase structure and microstructure evolution of the samples during the hot corrosion testing were analyzed with X-ray diffraction (XRD), Raman spectra, scanning electron microscopy (SEM), energy dispersive X-ray spectrum (EDS), and X-ray photoelectron spectroscopy (XPS). Results showed that the destabilization of SCZ ceramics at 750 °C was the result of the chemical reaction with V₂O₅ to produce m-ZrO₂ and CeVO₄, and little ScVO₄ was detected in the Sc₂O₃-rich SCZ ceramics. The primary corrosion products at 900 °C and 1100 °C were CeO₂ and m-ZrO₂ due to the mineralization effect. The Sc₂O₃-rich SCZ ceramics exhibited excellent degradation resistance and phase stability owing to the enhanced bond strength and the decreased size misfit between Zr⁴⁺ and Sc³⁺. The destabilization mechanism of SCZ ceramic under hot corrosion was also discussed.     

Facile Fabrication of Luminescent Eu(III) Functionalized HOF Hydrogel Film with Multifunctionailities: Quinolones Fluorescent Sensor and Anticounterfeiting Platform

The luminescent hydrogen-bonded organic framework (HOF) based films have become one of the most remarkable materials for optical application, thus, developing facile synthesis methods and establishing multifunctional applications for HOF-based luminescent materials are essential. Herein, a dual-emitting Eu³⁺-functionalized HOF hydrogel film ( 1 ) is fabricated successfully. 1 emits a blue-green long afterglow when turning off the UV lamp, and the long afterglow lifetime gets to 1.99 s. 1 performs great selectivity, high sensitivity, and low detection limit toward ofloxacin and flumequine, and the sensing toward ofloxacin and flumequine is in accord with the chroma and ratio modes. The fluorescent response mechanisms of 1  toward ofloxacin and flumequine are investigated in depth, which are further utilized to build an anticounterfeiting platform with high-level security. The film-based anticounterfeiting platform can conduct information encryption on demand inline with different fluorescent responses and can also fetch specific information by controlling the long afterglow intensity and excited light. This study not only provides a representative case of the fabrication of dual-emitting Eu³⁺-functionalized HOF-based hydrogel film but also opens the possibility of HOF-based film as intelligent luminescent materials with multifunctionalities.     

Synergistic effect of bulk phase doping and layered-spinel structure formation on improving electrochemical performance of Li-Rich cathode material

In this study, La was doped into the lithium layer of Li-rich cathode material and formed a layered-spinel hetero-structure. The morphology, crystal structure, element valence and kinetics of lithium ion migration were studied by field emission scanning electron microscope (FESEM), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and electrochemical impedance spectroscopy (EIS). The La doped lithium-rich cathode material exhibited similar initial discharge capacity of 262.8 mAh g^?1 at 0.1 C compared with the undoped material, but the discharge capacity retention rate can be obviously improved to 90% after 50 cycles at 1.0 C. Besides that, much better rate capability and Li⁺ diffusion coefficient were observed. The results revealed that La doping not only stabilized the material structure and reduced the Li/Ni mixing degree, but also induced the generation of spinel phase to provide three-dimensional diffusion channels for lithium ion migration. Moreover, the porous structure of the doped samples also contributed to the remarkable excellent electrochemical performance. All of these factors combined to significantly improve the electrochemical performance of the material.     

基于数据融合与迁移学习的学生表情识别研究

学生表情逐渐成为感知学生状态的重要途径,因此准确的识别学生表情因具有重要价值而受到广泛的关注.本文针对学生表情识别这一问题,提出基于数据融合与迁移学习的识别模型,该模型融合3个数据集,以解决学生表情数据缺乏与多样性问题,同时引入迁移学习来提升预测精度.在数据集及实际学生表情图像上的实验结果表明,本文提出的模型可以准确识别学生表情,提升了预测精度.     

用COMSOL实现圆波导中电磁波的可视化

为了直观描述金属圆波导中电磁场复杂的空间分布,本文用Comsol软件对金属圆波导中的TE11模、TE01模、和TM01模的电磁场结构进行动态仿真.将电磁场中的抽象概念形象化、可视化,使学生看清电磁场分布的宏观概况和细节变化,开拓了视野,同时加深了学生对电磁波传播特性的理解.     

国内外主要粟类作物的种植、研究及产业化概况（网络首发、推荐阅读）

粟类作物是一类籽粒小、抗旱、耐贫瘠的一年生作物的统称，多种植和消费在亚洲和非洲的发展中国家，我国栽培面积比较大的是谷子和糜子。与种植和消费情况不同，亚洲、欧洲和美洲相对发达国家的政府更重视粟类作物的科学研究及其科研投入。我国国家自然科学基金资助发表的粟类研究论文居世界之首，欧洲委员会、英国研究与创新署、美国国家科学基金会资助的粟类研究论文数量排名紧跟其后。梳理了近5年发表的粟类科研论文，印度最多，其次是我国和美国。基于粟类作物富含膳食纤维、蛋白质、矿物质、多酚等，其具有多方面的健康功效，因此粟类的食品科学技术和植物科学成为最热的研究领域。最后阐述了国内外传统的和工业化的粟类产品情况。     

西藏燕麦主要种植区灌溉定额空间分布及影响因素

燕麦为西藏自治区典型牧草之一,由于种植区地域辽阔,灌溉试验结果受限,西藏燕麦主要种植区的灌溉定额尚不明确。本文在西藏燕麦主要种植区内选取28个典型站点进行资料收集,遵循农业气候相似原则进行区域划分,基于水量平衡法揭示了西藏燕麦主要种植区灌溉定额的空间分布特征,并根据统计学原理分析了其影响因素。研究表明:燕麦主要种植区的灌溉定额呈由西藏中部至东部呈现先递增后递减的趋势,50%水文年下的燕麦灌溉定额在56~265 mm之间变化。降雨量是影响研究区内燕麦灌溉定额的主要因素(R²为0.515),ET₀次之(R²为0.152);其它气象因素中,日照时数对研究区燕麦灌溉定额影响较大(R²为0.462),且呈正相关关系;相对湿度对燕麦灌溉定额影响较小。西藏燕麦主要种植区的灌溉定额及其空间分布可为西藏自治区灌溉用水管理提供支撑。